Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate

In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra­molecular N—H⋯O inter­actions are present. In the crystal structure, the mol­ecules are linked through inter­molecular C—H⋯O inter­actions. The cr...

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Detalles Bibliográficos
Autores principales: Liu, Qiao-Ru, Chu, Song-Mao, Zhao, Gan-Qing, Chen, Li-Hua, Han, Yong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971360/
https://www.ncbi.nlm.nih.gov/pubmed/21578442
http://dx.doi.org/10.1107/S160053680904272X
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author Liu, Qiao-Ru
Chu, Song-Mao
Zhao, Gan-Qing
Chen, Li-Hua
Han, Yong-Jun
author_facet Liu, Qiao-Ru
Chu, Song-Mao
Zhao, Gan-Qing
Chen, Li-Hua
Han, Yong-Jun
author_sort Liu, Qiao-Ru
collection PubMed
description In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra­molecular N—H⋯O inter­actions are present. In the crystal structure, the mol­ecules are linked through inter­molecular C—H⋯O inter­actions. The crystal structure is also stabilized by C—H⋯π inter­actions and weak π–π contacts [centroid-centroid distance = 3.36 (6) Å].
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spelling pubmed-29713602010-12-30 Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate Liu, Qiao-Ru Chu, Song-Mao Zhao, Gan-Qing Chen, Li-Hua Han, Yong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra­molecular N—H⋯O inter­actions are present. In the crystal structure, the mol­ecules are linked through inter­molecular C—H⋯O inter­actions. The crystal structure is also stabilized by C—H⋯π inter­actions and weak π–π contacts [centroid-centroid distance = 3.36 (6) Å]. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971360/ /pubmed/21578442 http://dx.doi.org/10.1107/S160053680904272X Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Qiao-Ru
Chu, Song-Mao
Zhao, Gan-Qing
Chen, Li-Hua
Han, Yong-Jun
Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title_full Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title_fullStr Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title_full_unstemmed Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title_short Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
title_sort benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971360/
https://www.ncbi.nlm.nih.gov/pubmed/21578442
http://dx.doi.org/10.1107/S160053680904272X
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