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Diammonium 1,1′,3,3′-tetra­methyl-2,2′,4,4′,6,6′-hexa­oxoperhydro-5,5′-bipyrimidine-5,5′-diide monohydrate

In the title hydrated salt, 2NH(4) (+)·C(12)H(12)N(4)O(6) (2−)·H(2)O, the two hexa­hydro­pyrimidine rings in the dianion are inclined to one another at a dihedral angle of 62.76 (5)°. In the crystal structure, the anions and water mol­ecules are linked into sheets parallel to the bc plane by inter­m...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Reddy, B. Palakshi, Vijayakumar, V., Sarveswari, S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971361/
https://www.ncbi.nlm.nih.gov/pubmed/21578268
http://dx.doi.org/10.1107/S1600536809039968
Descripción
Sumario:In the title hydrated salt, 2NH(4) (+)·C(12)H(12)N(4)O(6) (2−)·H(2)O, the two hexa­hydro­pyrimidine rings in the dianion are inclined to one another at a dihedral angle of 62.76 (5)°. In the crystal structure, the anions and water mol­ecules are linked into sheets parallel to the bc plane by inter­molecular O—H⋯O hydrogen bonds and sustained by C—H⋯O contacts. The linking of the anions and water mol­ecules with the cations by N—H⋯O hydrogen bonds creates a three-dimensional extended network. The crystal structure is further stabilized by very weak C—H⋯π inter­actions.