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Diammonium 1,1′,3,3′-tetramethyl-2,2′,4,4′,6,6′-hexaoxoperhydro-5,5′-bipyrimidine-5,5′-diide monohydrate
In the title hydrated salt, 2NH(4) (+)·C(12)H(12)N(4)O(6) (2−)·H(2)O, the two hexahydropyrimidine rings in the dianion are inclined to one another at a dihedral angle of 62.76 (5)°. In the crystal structure, the anions and water molecules are linked into sheets parallel to the bc plane by interm...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971361/ https://www.ncbi.nlm.nih.gov/pubmed/21578268 http://dx.doi.org/10.1107/S1600536809039968 |
Sumario: | In the title hydrated salt, 2NH(4) (+)·C(12)H(12)N(4)O(6) (2−)·H(2)O, the two hexahydropyrimidine rings in the dianion are inclined to one another at a dihedral angle of 62.76 (5)°. In the crystal structure, the anions and water molecules are linked into sheets parallel to the bc plane by intermolecular O—H⋯O hydrogen bonds and sustained by C—H⋯O contacts. The linking of the anions and water molecules with the cations by N—H⋯O hydrogen bonds creates a three-dimensional extended network. The crystal structure is further stabilized by very weak C—H⋯π interactions. |
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