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Bis(ethylenediamine-κ(2) N,N′)bis(phenytoinato-κN)cobalt(II)
The title compound [systematic name: bis(2,5-dioxo-4,4-diphenylimidazolidin-1-ido-κN (1))bis(ethylenediamine-κ(2) N,N′)cobalt(II)], [Co(C(15)H(11)N(2)O(2))(2)(C(2)H(8)N(2))(2)], has site symmetry [Image: see text]. The Co(II) cation is located on an inversion center and coordinated by two phenytoin...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971365/ https://www.ncbi.nlm.nih.gov/pubmed/21578194 http://dx.doi.org/10.1107/S1600536809044092 |
| _version_ | 1782190610357157888 |
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| author | Hu, Xi-Lan Xu, Xing-You Wang, Da-Qi Zhou, Yan-Qin |
| author_facet | Hu, Xi-Lan Xu, Xing-You Wang, Da-Qi Zhou, Yan-Qin |
| author_sort | Hu, Xi-Lan |
| collection | PubMed |
| description | The title compound [systematic name: bis(2,5-dioxo-4,4-diphenylimidazolidin-1-ido-κN (1))bis(ethylenediamine-κ(2) N,N′)cobalt(II)], [Co(C(15)H(11)N(2)O(2))(2)(C(2)H(8)N(2))(2)], has site symmetry [Image: see text]. The Co(II) cation is located on an inversion center and coordinated by two phenytoin anions and two ethylenediamine ligands in a distorted octahedral geometry. In the phenytoin anion, the two phenyl rings are twisted with respect to the central hydantoin ring, making dihedral angles of 77.49 (16) and 64.55 (15)°. Intramolecular and intermolecular N—H⋯O hydrogen bonding is present in the crystal structure. |
| format | Text |
| id | pubmed-2971365 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29713652010-12-30 Bis(ethylenediamine-κ(2) N,N′)bis(phenytoinato-κN)cobalt(II) Hu, Xi-Lan Xu, Xing-You Wang, Da-Qi Zhou, Yan-Qin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound [systematic name: bis(2,5-dioxo-4,4-diphenylimidazolidin-1-ido-κN (1))bis(ethylenediamine-κ(2) N,N′)cobalt(II)], [Co(C(15)H(11)N(2)O(2))(2)(C(2)H(8)N(2))(2)], has site symmetry [Image: see text]. The Co(II) cation is located on an inversion center and coordinated by two phenytoin anions and two ethylenediamine ligands in a distorted octahedral geometry. In the phenytoin anion, the two phenyl rings are twisted with respect to the central hydantoin ring, making dihedral angles of 77.49 (16) and 64.55 (15)°. Intramolecular and intermolecular N—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971365/ /pubmed/21578194 http://dx.doi.org/10.1107/S1600536809044092 Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hu, Xi-Lan Xu, Xing-You Wang, Da-Qi Zhou, Yan-Qin Bis(ethylenediamine-κ(2) N,N′)bis(phenytoinato-κN)cobalt(II) |
| title | Bis(ethylenediamine-κ(2)
N,N′)bis(phenytoinato-κN)cobalt(II) |
| title_full | Bis(ethylenediamine-κ(2)
N,N′)bis(phenytoinato-κN)cobalt(II) |
| title_fullStr | Bis(ethylenediamine-κ(2)
N,N′)bis(phenytoinato-κN)cobalt(II) |
| title_full_unstemmed | Bis(ethylenediamine-κ(2)
N,N′)bis(phenytoinato-κN)cobalt(II) |
| title_short | Bis(ethylenediamine-κ(2)
N,N′)bis(phenytoinato-κN)cobalt(II) |
| title_sort | bis(ethylenediamine-κ(2)
n,n′)bis(phenytoinato-κn)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971365/ https://www.ncbi.nlm.nih.gov/pubmed/21578194 http://dx.doi.org/10.1107/S1600536809044092 |
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