Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)

In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl­ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra­molecular C—H⋯O inter­actions occur. The mol­e...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Wang, Chuanhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971366/
https://www.ncbi.nlm.nih.gov/pubmed/21578174
http://dx.doi.org/10.1107/S1600536809043578
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author Wen, Liyuan
Yin, Handong
Wang, Chuanhua
author_facet Wen, Liyuan
Yin, Handong
Wang, Chuanhua
author_sort Wen, Liyuan
collection PubMed
description In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl­ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra­molecular C—H⋯O inter­actions occur. The mol­ecules are connected by inter­molecular N—H⋯O, N—H⋯N and C—H⋯O hydrogen-bonding inter­actions and C—H⋯π stacking inter­actions, forming a three-dimensional supra­molecular framework
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spelling pubmed-29713662010-12-30 Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V) Wen, Liyuan Yin, Handong Wang, Chuanhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl­ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra­molecular C—H⋯O inter­actions occur. The mol­ecules are connected by inter­molecular N—H⋯O, N—H⋯N and C—H⋯O hydrogen-bonding inter­actions and C—H⋯π stacking inter­actions, forming a three-dimensional supra­molecular framework International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971366/ /pubmed/21578174 http://dx.doi.org/10.1107/S1600536809043578 Text en © Wen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Liyuan
Yin, Handong
Wang, Chuanhua
Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title_full Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title_fullStr Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title_full_unstemmed Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title_short Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)
title_sort bis(5-amino-2-chloro­benzoato-κo)triphenyl­anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971366/
https://www.ncbi.nlm.nih.gov/pubmed/21578174
http://dx.doi.org/10.1107/S1600536809043578
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AT wangchuanhua bis5amino2chlorobenzoatokotriphenylantimonyv

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