{2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)

The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl­aluminum in tetra­hydro­furan. The ligands adopt a distorted tetra­hedral geometry around aluminium. Obvious hydrogen-bonding interacti...

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Detalles Bibliográficos
Autores principales: Eisenberg, Audrey C., Tanski, Joseph M., Getzler, Yutan D. Y. L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971370/
https://www.ncbi.nlm.nih.gov/pubmed/21578108
http://dx.doi.org/10.1107/S1600536809040598
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author Eisenberg, Audrey C.
Tanski, Joseph M.
Getzler, Yutan D. Y. L.
author_facet Eisenberg, Audrey C.
Tanski, Joseph M.
Getzler, Yutan D. Y. L.
author_sort Eisenberg, Audrey C.
collection PubMed
description The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl­aluminum in tetra­hydro­furan. The ligands adopt a distorted tetra­hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present.
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spelling pubmed-29713702010-12-30 {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III) Eisenberg, Audrey C. Tanski, Joseph M. Getzler, Yutan D. Y. L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl­aluminum in tetra­hydro­furan. The ligands adopt a distorted tetra­hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971370/ /pubmed/21578108 http://dx.doi.org/10.1107/S1600536809040598 Text en © Eisenberg et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eisenberg, Audrey C.
Tanski, Joseph M.
Getzler, Yutan D. Y. L.
{2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title_full {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title_fullStr {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title_full_unstemmed {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title_short {2-[Bis(3-methyl-1H-indol-2-yl)meth­yl]phenolato-κO}dimeth­yl(tetra­hydro­furan-κO)aluminium(III)
title_sort {2-[bis(3-methyl-1h-indol-2-yl)meth­yl]phenolato-κo}dimeth­yl(tetra­hydro­furan-κo)aluminium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971370/
https://www.ncbi.nlm.nih.gov/pubmed/21578108
http://dx.doi.org/10.1107/S1600536809040598
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AT getzleryutandyl 2bis3methyl1hindol2ylmethylphenolatokodimethyltetrahydrofurankoaluminiumiii

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