A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate

The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C(20)H(14)N(2)O(4))]·2CH(3)OH, was obtained by the reaction of 2,4-dihydroxy­benzaldehyde and 1,2-phenyl­enediamine with nickel(II) acetate. The Ni(II) atom is coordinated by two N atoms [Ni—N = 1.839 (2) Å] and two O atoms [Ni—O = 1.8...

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Detalles Bibliográficos
Autores principales: Niu, Meiju, Liu, Guihua, Wang, Daqi, Dou, Jianmin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971377/
https://www.ncbi.nlm.nih.gov/pubmed/21578111
http://dx.doi.org/10.1107/S160053680904063X
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author Niu, Meiju
Liu, Guihua
Wang, Daqi
Dou, Jianmin
author_facet Niu, Meiju
Liu, Guihua
Wang, Daqi
Dou, Jianmin
author_sort Niu, Meiju
collection PubMed
description The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C(20)H(14)N(2)O(4))]·2CH(3)OH, was obtained by the reaction of 2,4-dihydroxy­benzaldehyde and 1,2-phenyl­enediamine with nickel(II) acetate. The Ni(II) atom is coordinated by two N atoms [Ni—N = 1.839 (2) Å] and two O atoms [Ni—O = 1.8253 (19) Å] in an approximately square-planar geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a chain along [001].
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spelling pubmed-29713772010-12-30 A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate Niu, Meiju Liu, Guihua Wang, Daqi Dou, Jianmin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C(20)H(14)N(2)O(4))]·2CH(3)OH, was obtained by the reaction of 2,4-dihydroxy­benzaldehyde and 1,2-phenyl­enediamine with nickel(II) acetate. The Ni(II) atom is coordinated by two N atoms [Ni—N = 1.839 (2) Å] and two O atoms [Ni—O = 1.8253 (19) Å] in an approximately square-planar geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a chain along [001]. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971377/ /pubmed/21578111 http://dx.doi.org/10.1107/S160053680904063X Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Meiju
Liu, Guihua
Wang, Daqi
Dou, Jianmin
A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title_full A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title_fullStr A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title_full_unstemmed A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title_short A new Schiff base nickel(II) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) methanol disolvate
title_sort new schiff base nickel(ii) complex: {5,5′-dihydr­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971377/
https://www.ncbi.nlm.nih.gov/pubmed/21578111
http://dx.doi.org/10.1107/S160053680904063X
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