μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]

The title compound, [Sn(2)(C(6)H(5))(6)(C(8)H(5)NO(4))], contains two triphenyl­tin groups bridged by a 2-amino­terephthalate ligand. The two Sn(IV) centers have similar distorted tetra­hedral coordination geometries. Each Sn(IV) atom is bonded to three phenyl C atoms and one O atom from a carboxyl­...

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Detalles Bibliográficos
Autores principales: Li, Wenkuan, Yin, Handong, Dong, Lei, Li, Jing, Zhang, Qijun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971378/
https://www.ncbi.nlm.nih.gov/pubmed/21578180
http://dx.doi.org/10.1107/S1600536809043554
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author Li, Wenkuan
Yin, Handong
Dong, Lei
Li, Jing
Zhang, Qijun
author_facet Li, Wenkuan
Yin, Handong
Dong, Lei
Li, Jing
Zhang, Qijun
author_sort Li, Wenkuan
collection PubMed
description The title compound, [Sn(2)(C(6)H(5))(6)(C(8)H(5)NO(4))], contains two triphenyl­tin groups bridged by a 2-amino­terephthalate ligand. The two Sn(IV) centers have similar distorted tetra­hedral coordination geometries. Each Sn(IV) atom is bonded to three phenyl C atoms and one O atom from a carboxyl­ate group. The other O atom of the carboxyl­ate group has a weak inter­action with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intra­molecular N—H⋯O hydrogen bonds are observed.
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spelling pubmed-29713782010-12-30 μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)] Li, Wenkuan Yin, Handong Dong, Lei Li, Jing Zhang, Qijun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(2)(C(6)H(5))(6)(C(8)H(5)NO(4))], contains two triphenyl­tin groups bridged by a 2-amino­terephthalate ligand. The two Sn(IV) centers have similar distorted tetra­hedral coordination geometries. Each Sn(IV) atom is bonded to three phenyl C atoms and one O atom from a carboxyl­ate group. The other O atom of the carboxyl­ate group has a weak inter­action with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intra­molecular N—H⋯O hydrogen bonds are observed. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971378/ /pubmed/21578180 http://dx.doi.org/10.1107/S1600536809043554 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wenkuan
Yin, Handong
Dong, Lei
Li, Jing
Zhang, Qijun
μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title_full μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title_fullStr μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title_full_unstemmed μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title_short μ-2-Amino­terephthalato-κ(2) O (1):O (4)-bis­[triphenyl­tin(IV)]
title_sort μ-2-amino­terephthalato-κ(2) o (1):o (4)-bis­[triphenyl­tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971378/
https://www.ncbi.nlm.nih.gov/pubmed/21578180
http://dx.doi.org/10.1107/S1600536809043554
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