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Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971379/ https://www.ncbi.nlm.nih.gov/pubmed/21578211 http://dx.doi.org/10.1107/S1600536809042755 |
Sumario: | In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water molecule occupying the apical position. Neighbouring complexes are connected via O—H⋯O hydrogen bonds between the water molecule and the methoxy group, forming a chain structure along the a axis. The propylene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin. |
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