Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol...
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Formato: | Texto |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971379/ https://www.ncbi.nlm.nih.gov/pubmed/21578211 http://dx.doi.org/10.1107/S1600536809042755 |
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author | Wang, Hui |
author_facet | Wang, Hui |
author_sort | Wang, Hui |
collection | PubMed |
description | In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water molecule occupying the apical position. Neighbouring complexes are connected via O—H⋯O hydrogen bonds between the water molecule and the methoxy group, forming a chain structure along the a axis. The propylene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin. |
format | Text |
id | pubmed-2971379 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713792010-12-30 Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) Wang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water molecule occupying the apical position. Neighbouring complexes are connected via O—H⋯O hydrogen bonds between the water molecule and the methoxy group, forming a chain structure along the a axis. The propylene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971379/ /pubmed/21578211 http://dx.doi.org/10.1107/S1600536809042755 Text en © Hui Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Hui Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title | Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_full | Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_fullStr | Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_full_unstemmed | Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_short | Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_sort | aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971379/ https://www.ncbi.nlm.nih.gov/pubmed/21578211 http://dx.doi.org/10.1107/S1600536809042755 |
work_keys_str_mv | AT wanghui aqua66dimethoxy22propane13diylbisnitrilomethylidynediphenolatocopperii |