Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)

In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol...

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Autor principal: Wang, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971379/
https://www.ncbi.nlm.nih.gov/pubmed/21578211
http://dx.doi.org/10.1107/S1600536809042755
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author Wang, Hui
author_facet Wang, Hui
author_sort Wang, Hui
collection PubMed
description In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol­ecule occupying the apical position. Neighbouring complexes are connected via O—H⋯O hydrogen bonds between the water mol­ecule and the meth­oxy group, forming a chain structure along the a axis. The propyl­ene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin.
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spelling pubmed-29713792010-12-30 Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) Wang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol­ecule occupying the apical position. Neighbouring complexes are connected via O—H⋯O hydrogen bonds between the water mol­ecule and the meth­oxy group, forming a chain structure along the a axis. The propyl­ene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971379/ /pubmed/21578211 http://dx.doi.org/10.1107/S1600536809042755 Text en © Hui Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hui
Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_fullStr Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full_unstemmed Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_short Aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_sort aqua{6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971379/
https://www.ncbi.nlm.nih.gov/pubmed/21578211
http://dx.doi.org/10.1107/S1600536809042755
work_keys_str_mv AT wanghui aqua66dimethoxy22propane13diylbisnitrilomethylidynediphenolatocopperii