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1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone
In the title compound, C(18)H(16)O(4), a monoprenylated xanthone, the xanthone skeleton exhibits an essentially planar conformation (r.m.s. deviation 0.0072 Å) and the isoprenyl side chain remains approximately in the mean plane of the xanthone unit, making a dihedral angle of 4.5 (2)°. The hydroxyl...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971381/ https://www.ncbi.nlm.nih.gov/pubmed/21578316 http://dx.doi.org/10.1107/S1600536809040069 |
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author | Gales, Luis Castanheiro, Raquel A. P. Pinto, Madalena M. M. Damas, Ana M. |
author_facet | Gales, Luis Castanheiro, Raquel A. P. Pinto, Madalena M. M. Damas, Ana M. |
author_sort | Gales, Luis |
collection | PubMed |
description | In the title compound, C(18)H(16)O(4), a monoprenylated xanthone, the xanthone skeleton exhibits an essentially planar conformation (r.m.s. deviation 0.0072 Å) and the isoprenyl side chain remains approximately in the mean plane of the xanthone unit, making a dihedral angle of 4.5 (2)°. The hydroxyl group forms an intramolecular O—H⋯O hydrogen bond. Moreover, there is a weak intermolecular C—H⋯O interaction between a ring C atom and the xanthene O atom. In the crystal structure, there are no intermolecular hydrogen bonds and the crystallographic packing is governed by van der Waals forces, leading to an arrangement in which the molecules assemble with their planes parallel to each other, having a separation of 3.6 (3) Å. |
format | Text |
id | pubmed-2971381 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713812010-12-30 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone Gales, Luis Castanheiro, Raquel A. P. Pinto, Madalena M. M. Damas, Ana M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)O(4), a monoprenylated xanthone, the xanthone skeleton exhibits an essentially planar conformation (r.m.s. deviation 0.0072 Å) and the isoprenyl side chain remains approximately in the mean plane of the xanthone unit, making a dihedral angle of 4.5 (2)°. The hydroxyl group forms an intramolecular O—H⋯O hydrogen bond. Moreover, there is a weak intermolecular C—H⋯O interaction between a ring C atom and the xanthene O atom. In the crystal structure, there are no intermolecular hydrogen bonds and the crystallographic packing is governed by van der Waals forces, leading to an arrangement in which the molecules assemble with their planes parallel to each other, having a separation of 3.6 (3) Å. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971381/ /pubmed/21578316 http://dx.doi.org/10.1107/S1600536809040069 Text en © Gales et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gales, Luis Castanheiro, Raquel A. P. Pinto, Madalena M. M. Damas, Ana M. 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title | 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title_full | 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title_fullStr | 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title_full_unstemmed | 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title_short | 1-Hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
title_sort | 1-hydroxy-3-(3-methylbut-2-enyloxy)xanthone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971381/ https://www.ncbi.nlm.nih.gov/pubmed/21578316 http://dx.doi.org/10.1107/S1600536809040069 |
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