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(4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate

The title compound, [Na(C(18)H(36)N(2)O(6))]ClO(4), was isolated and crystallized to understand more fully the ligand’s binding specificity to cations. The cation and anion reside at an inter­section of crystallographic twofold and threefold axes. The carbon atoms in the cation are disordered over t...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Su, Joe W., Spencer, Lara C., Burnette, Ronald R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971382/
https://www.ncbi.nlm.nih.gov/pubmed/21578130
http://dx.doi.org/10.1107/S1600536809039683
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author Guzei, Ilia A.
Su, Joe W.
Spencer, Lara C.
Burnette, Ronald R.
author_facet Guzei, Ilia A.
Su, Joe W.
Spencer, Lara C.
Burnette, Ronald R.
author_sort Guzei, Ilia A.
collection PubMed
description The title compound, [Na(C(18)H(36)N(2)O(6))]ClO(4), was isolated and crystallized to understand more fully the ligand’s binding specificity to cations. The cation and anion reside at an inter­section of crystallographic twofold and threefold axes. The carbon atoms in the cation are disordered over two positions in a 3:2 ratio, and the anion is equally disordered over two positions. The geometries of the cation and anion are typical. The compound packs in alternating sheets of discrete cations and anions stacked along the c axis, separated by a distance equal to one-sixth the length of the c axis.
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spelling pubmed-29713822010-12-30 (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate Guzei, Ilia A. Su, Joe W. Spencer, Lara C. Burnette, Ronald R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(C(18)H(36)N(2)O(6))]ClO(4), was isolated and crystallized to understand more fully the ligand’s binding specificity to cations. The cation and anion reside at an inter­section of crystallographic twofold and threefold axes. The carbon atoms in the cation are disordered over two positions in a 3:2 ratio, and the anion is equally disordered over two positions. The geometries of the cation and anion are typical. The compound packs in alternating sheets of discrete cations and anions stacked along the c axis, separated by a distance equal to one-sixth the length of the c axis. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971382/ /pubmed/21578130 http://dx.doi.org/10.1107/S1600536809039683 Text en © Guzei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Su, Joe W.
Spencer, Lara C.
Burnette, Ronald R.
(4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title_full (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title_fullStr (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title_full_unstemmed (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title_short (4,7,13,16,21,24-Hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
title_sort (4,7,13,16,21,24-hexaoxa-1,10-diaza­bicyclo­[8.8.8]hexa­cosa­ne)sodium perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971382/
https://www.ncbi.nlm.nih.gov/pubmed/21578130
http://dx.doi.org/10.1107/S1600536809039683
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