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Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetradentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxylate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971383/ https://www.ncbi.nlm.nih.gov/pubmed/21578052 http://dx.doi.org/10.1107/S1600536809039440 |
Sumario: | In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetradentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxylate O atom. The Cd(II) atom is connected via the carboxylate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. The Cd(II) atom is seven-coordinate in a pentagonal-bipyramidal geometry with four O atoms from two carboxylate groups and three aqua ligands. The heterotrinuclear molecules are linked to the uncoordinated water molecules by O—H⋯O hydrogen bonds into a three-dimensional framework. |
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