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Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate

In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra­dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl­ate...

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Detalles Bibliográficos
Autores principales: Jiang, Jiaxun, Lu, Yao, Yuan, Limin, Liu, Wenlong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971383/
https://www.ncbi.nlm.nih.gov/pubmed/21578052
http://dx.doi.org/10.1107/S1600536809039440
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author Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
author_facet Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
author_sort Jiang, Jiaxun
collection PubMed
description In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra­dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl­ate O atom. The Cd(II) atom is connected via the carboxyl­ate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. The Cd(II) atom is seven-coordinate in a penta­gonal-bipyramidal geometry with four O atoms from two carboxyl­ate groups and three aqua ligands. The heterotrinuclear mol­ecules are linked to the uncoordinated water mol­ecules by O—H⋯O hydrogen bonds into a three-dimensional framework.
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spelling pubmed-29713832010-12-30 Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra­dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl­ate O atom. The Cd(II) atom is connected via the carboxyl­ate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. The Cd(II) atom is seven-coordinate in a penta­gonal-bipyramidal geometry with four O atoms from two carboxyl­ate groups and three aqua ligands. The heterotrinuclear mol­ecules are linked to the uncoordinated water mol­ecules by O—H⋯O hydrogen bonds into a three-dimensional framework. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971383/ /pubmed/21578052 http://dx.doi.org/10.1107/S1600536809039440 Text en © Jiang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title_full Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title_fullStr Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title_full_unstemmed Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title_short Triaqua­bis{μ-N-[N-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
title_sort triaqua­bis{μ-n-[n-(4-meth­oxy-2-oxidobenzyl­idene)glyc­yl]glycinato(3−)}cadmium(ii)dicopper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971383/
https://www.ncbi.nlm.nih.gov/pubmed/21578052
http://dx.doi.org/10.1107/S1600536809039440
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