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Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetradentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxylate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971383/ https://www.ncbi.nlm.nih.gov/pubmed/21578052 http://dx.doi.org/10.1107/S1600536809039440 |
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author | Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong |
author_facet | Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong |
author_sort | Jiang, Jiaxun |
collection | PubMed |
description | In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetradentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxylate O atom. The Cd(II) atom is connected via the carboxylate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. The Cd(II) atom is seven-coordinate in a pentagonal-bipyramidal geometry with four O atoms from two carboxylate groups and three aqua ligands. The heterotrinuclear molecules are linked to the uncoordinated water molecules by O—H⋯O hydrogen bonds into a three-dimensional framework. |
format | Text |
id | pubmed-2971383 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713832010-12-30 Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetradentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxylate O atom. The Cd(II) atom is connected via the carboxylate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. The Cd(II) atom is seven-coordinate in a pentagonal-bipyramidal geometry with four O atoms from two carboxylate groups and three aqua ligands. The heterotrinuclear molecules are linked to the uncoordinated water molecules by O—H⋯O hydrogen bonds into a three-dimensional framework. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971383/ /pubmed/21578052 http://dx.doi.org/10.1107/S1600536809039440 Text en © Jiang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title | Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title_full | Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title_fullStr | Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title_full_unstemmed | Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title_short | Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate |
title_sort | triaquabis{μ-n-[n-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(ii)dicopper(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971383/ https://www.ncbi.nlm.nih.gov/pubmed/21578052 http://dx.doi.org/10.1107/S1600536809039440 |
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