2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one

The 1,3-dioxin-4-one ring in the title compound, C(16)H(16)O(3), is in a half-boat conformation with the quaternary O—C(CH(3))(2)—O atom lying 0.546 (1) Å out of the plane defined by the remaining five atoms. The crystal structure is consolidated by C—H⋯O contacts that lead to supra­molecular layers...

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Detalles Bibliográficos
Autores principales: Caracelli, Ignez, Zukerman-Schpector, Julio, Vieira, Adriano S., Stefani, Hélio A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971386/
https://www.ncbi.nlm.nih.gov/pubmed/21578331
http://dx.doi.org/10.1107/S1600536809041002
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author Caracelli, Ignez
Zukerman-Schpector, Julio
Vieira, Adriano S.
Stefani, Hélio A.
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Zukerman-Schpector, Julio
Vieira, Adriano S.
Stefani, Hélio A.
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The 1,3-dioxin-4-one ring in the title compound, C(16)H(16)O(3), is in a half-boat conformation with the quaternary O—C(CH(3))(2)—O atom lying 0.546 (1) Å out of the plane defined by the remaining five atoms. The crystal structure is consolidated by C—H⋯O contacts that lead to supra­molecular layers.
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spelling pubmed-29713862010-12-30 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one Caracelli, Ignez Zukerman-Schpector, Julio Vieira, Adriano S. Stefani, Hélio A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 1,3-dioxin-4-one ring in the title compound, C(16)H(16)O(3), is in a half-boat conformation with the quaternary O—C(CH(3))(2)—O atom lying 0.546 (1) Å out of the plane defined by the remaining five atoms. The crystal structure is consolidated by C—H⋯O contacts that lead to supra­molecular layers. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971386/ /pubmed/21578331 http://dx.doi.org/10.1107/S1600536809041002 Text en © Caracelli et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Zukerman-Schpector, Julio
Vieira, Adriano S.
Stefani, Hélio A.
Tiekink, Edward R. T.
2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title_full 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title_fullStr 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title_full_unstemmed 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title_short 2,2,6-Trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4H-1,3-dioxin-4-one
title_sort 2,2,6-trimethyl-5-[2-(4-methyl­phen­yl)ethyn­yl]-4h-1,3-dioxin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971386/
https://www.ncbi.nlm.nih.gov/pubmed/21578331
http://dx.doi.org/10.1107/S1600536809041002
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