Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)

In the title compound, [Cu(C(2)Cl(3)O(2))(2)(C(6)H(12)N(4))(2)], the Cu(II) ion (site symmetry 2) is coordinated by two trichloro­acetate anions and two hexa­methyl­enetetra­mine mol­ecules, resulting in a distorted CuN(2)O(2) geometry that is inter­mediate between tetra­hedral and square planar. Th...

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Detalles Bibliográficos
Autores principales: Li, Li-Min, Jian, Fang-Fang, Li, Yu-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971390/
https://www.ncbi.nlm.nih.gov/pubmed/21578193
http://dx.doi.org/10.1107/S1600536809043736
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author Li, Li-Min
Jian, Fang-Fang
Li, Yu-Feng
author_facet Li, Li-Min
Jian, Fang-Fang
Li, Yu-Feng
author_sort Li, Li-Min
collection PubMed
description In the title compound, [Cu(C(2)Cl(3)O(2))(2)(C(6)H(12)N(4))(2)], the Cu(II) ion (site symmetry 2) is coordinated by two trichloro­acetate anions and two hexa­methyl­enetetra­mine mol­ecules, resulting in a distorted CuN(2)O(2) geometry that is inter­mediate between tetra­hedral and square planar. The Cl atoms are disordered over two sets of sites, with relative occupancies of 0.749 (7) and 0.251 (7). In the crystal, the packing is consolidated by inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29713902010-12-30 Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II) Li, Li-Min Jian, Fang-Fang Li, Yu-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)Cl(3)O(2))(2)(C(6)H(12)N(4))(2)], the Cu(II) ion (site symmetry 2) is coordinated by two trichloro­acetate anions and two hexa­methyl­enetetra­mine mol­ecules, resulting in a distorted CuN(2)O(2) geometry that is inter­mediate between tetra­hedral and square planar. The Cl atoms are disordered over two sets of sites, with relative occupancies of 0.749 (7) and 0.251 (7). In the crystal, the packing is consolidated by inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971390/ /pubmed/21578193 http://dx.doi.org/10.1107/S1600536809043736 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Li-Min
Jian, Fang-Fang
Li, Yu-Feng
Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title_full Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title_fullStr Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title_full_unstemmed Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title_short Bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(II)
title_sort bis(hexa­methyl­enetetra­mine)bis­(tri­chloro­acetato)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971390/
https://www.ncbi.nlm.nih.gov/pubmed/21578193
http://dx.doi.org/10.1107/S1600536809043736
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AT jianfangfang bishexamethylenetetraminebistrichloroacetatocopperii
AT liyufeng bishexamethylenetetraminebistrichloroacetatocopperii

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