Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate

The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenol (HL) ligands, three independent thio­cyanate anions and an uncoordinated water mol­ecule. The Pr(III) ion is nine-coordinated. The thio­cy...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971403/
https://www.ncbi.nlm.nih.gov/pubmed/21578043
http://dx.doi.org/10.1107/S1600536809038823
Descripción
Sumario:The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenol (HL) ligands, three independent thio­cyanate anions and an uncoordinated water mol­ecule. The Pr(III) ion is nine-coordinated. The thio­cyanate anions coordinate to the Pr(III) ion via the N atoms and the three HL ligands chelate the Pr(III) ion via the phenoxy and meth­oxy O atoms. The protonated imine N atoms are involved in intra­molecular hydrogen bonds with the phenolate groups.

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