Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate

The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenol (HL) ligands, three independent thio­cyanate anions and an uncoordinated water mol­ecule. The Pr(III) ion is nine-coordinated. The thio­cy...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971403/
https://www.ncbi.nlm.nih.gov/pubmed/21578043
http://dx.doi.org/10.1107/S1600536809038823
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author Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
author_facet Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
author_sort Liu, Jian-Feng
collection PubMed
description The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenol (HL) ligands, three independent thio­cyanate anions and an uncoordinated water mol­ecule. The Pr(III) ion is nine-coordinated. The thio­cyanate anions coordinate to the Pr(III) ion via the N atoms and the three HL ligands chelate the Pr(III) ion via the phenoxy and meth­oxy O atoms. The protonated imine N atoms are involved in intra­molecular hydrogen bonds with the phenolate groups.
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spelling pubmed-29714032010-12-30 Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [Pr(NCS)(3)(C(15)H(15)NO(2))(3)]·H(2)O, consists of three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenol (HL) ligands, three independent thio­cyanate anions and an uncoordinated water mol­ecule. The Pr(III) ion is nine-coordinated. The thio­cyanate anions coordinate to the Pr(III) ion via the N atoms and the three HL ligands chelate the Pr(III) ion via the phenoxy and meth­oxy O atoms. The protonated imine N atoms are involved in intra­molecular hydrogen bonds with the phenolate groups. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971403/ /pubmed/21578043 http://dx.doi.org/10.1107/S1600536809038823 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jian-Feng
Liu, Jia-Lu
Zhao, Guo-Liang
Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title_full Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title_fullStr Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title_full_unstemmed Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title_short Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(thio­cyanato-κN)praseodymium(III) monohydrate
title_sort tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) o,o′}tris­(thio­cyanato-κn)praseodymium(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971403/
https://www.ncbi.nlm.nih.gov/pubmed/21578043
http://dx.doi.org/10.1107/S1600536809038823
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AT liujialu tris2methoxy64methylphenyliminiomethylphenolatok2ootristhiocyanatoknpraseodymiumiiimonohydrate
AT zhaoguoliang tris2methoxy64methylphenyliminiomethylphenolatok2ootristhiocyanatoknpraseodymiumiiimonohydrate

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