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3-Hydroxy-N′-[(Z)-(5-methyl-2-furyl)methylidene]naphthalene-2-carbohydrazide
The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent molecules. In one of these molecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered molecules, the furan and naphthalene rings...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971404/ https://www.ncbi.nlm.nih.gov/pubmed/21578435 http://dx.doi.org/10.1107/S1600536809043141 |
Sumario: | The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent molecules. In one of these molecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered molecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered molecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. An intramolecular O—H⋯O hydrogen bond occurs within each molecule. In the crystal, molecules are linked by N—H⋯O, N—H⋯(N,O) and C—H⋯O interactions. |
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