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3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide

The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol­ecules. In one of these mol­ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol­ecules, the furan and naphthalene rings...

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Detalles Bibliográficos
Autores principales: Shafiq, Zahid, Yaqub, Muhammad, Tahir, M. Nawaz, Nawaz, Mian Hasnain, Iqbal, M. Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971404/
https://www.ncbi.nlm.nih.gov/pubmed/21578435
http://dx.doi.org/10.1107/S1600536809043141
Descripción
Sumario:The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol­ecules. In one of these mol­ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol­ecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered mol­ecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. An intra­molecular O—H⋯O hydrogen bond occurs within each mol­ecule. In the crystal, mol­ecules are linked by N—H⋯O, N—H⋯(N,O) and C—H⋯O inter­actions.