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3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide

The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol­ecules. In one of these mol­ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol­ecules, the furan and naphthalene rings...

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Autores principales: Shafiq, Zahid, Yaqub, Muhammad, Tahir, M. Nawaz, Nawaz, Mian Hasnain, Iqbal, M. Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971404/
https://www.ncbi.nlm.nih.gov/pubmed/21578435
http://dx.doi.org/10.1107/S1600536809043141
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author Shafiq, Zahid
Yaqub, Muhammad
Tahir, M. Nawaz
Nawaz, Mian Hasnain
Iqbal, M. Saeed
author_facet Shafiq, Zahid
Yaqub, Muhammad
Tahir, M. Nawaz
Nawaz, Mian Hasnain
Iqbal, M. Saeed
author_sort Shafiq, Zahid
collection PubMed
description The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol­ecules. In one of these mol­ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol­ecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered mol­ecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. An intra­molecular O—H⋯O hydrogen bond occurs within each mol­ecule. In the crystal, mol­ecules are linked by N—H⋯O, N—H⋯(N,O) and C—H⋯O inter­actions.
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spelling pubmed-29714042010-12-30 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide Shafiq, Zahid Yaqub, Muhammad Tahir, M. Nawaz Nawaz, Mian Hasnain Iqbal, M. Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of title compound, C(17)H(14)N(2)O(3), contains three independent mol­ecules. In one of these mol­ecules, the 5-methyl-2-furyl group is disordered over two sets of sites with an occupancy ratio of 0.747 (3):0.253 (3). In the two ordered mol­ecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered mol­ecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. An intra­molecular O—H⋯O hydrogen bond occurs within each mol­ecule. In the crystal, mol­ecules are linked by N—H⋯O, N—H⋯(N,O) and C—H⋯O inter­actions. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971404/ /pubmed/21578435 http://dx.doi.org/10.1107/S1600536809043141 Text en © Shafiq et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Zahid
Yaqub, Muhammad
Tahir, M. Nawaz
Nawaz, Mian Hasnain
Iqbal, M. Saeed
3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title_full 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title_fullStr 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title_full_unstemmed 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title_short 3-Hydr­oxy-N′-[(Z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
title_sort 3-hydr­oxy-n′-[(z)-(5-methyl-2-fur­yl)methyl­idene]naphthalene-2-carbo­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971404/
https://www.ncbi.nlm.nih.gov/pubmed/21578435
http://dx.doi.org/10.1107/S1600536809043141
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