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Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV)
The title tetranuclear Sn(IV) compound, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)], has site symmetry [Image: see text]. Two O(2−) and two OH(−) anions bridge four Sn(IV) cations to form the tetranuclear compound. The two independent Sn(IV) cations assume SnO(3)C(2) and SnO(2)C(2)Cl distorted trigonal...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971409/ https://www.ncbi.nlm.nih.gov/pubmed/21578215 http://dx.doi.org/10.1107/S1600536809045176 |
| _version_ | 1782190620802023424 |
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| author | Zhang, Qi-Jun Yin, Han-Dong Wen, Li-Yuan Wang, Da-Qi |
| author_facet | Zhang, Qi-Jun Yin, Han-Dong Wen, Li-Yuan Wang, Da-Qi |
| author_sort | Zhang, Qi-Jun |
| collection | PubMed |
| description | The title tetranuclear Sn(IV) compound, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)], has site symmetry [Image: see text]. Two O(2−) and two OH(−) anions bridge four Sn(IV) cations to form the tetranuclear compound. The two independent Sn(IV) cations assume SnO(3)C(2) and SnO(2)C(2)Cl distorted trigonal-bipyramidal coordination geometries. Intramolecular O—H⋯Cl hydrogen bonding is present in the structure. One Cl atom of a chlorobenzyl ligand is disordered over two sites with an occupancy ratio of 0.693 (2):0.307 (2). |
| format | Text |
| id | pubmed-2971409 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29714092010-12-30 Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) Zhang, Qi-Jun Yin, Han-Dong Wen, Li-Yuan Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title tetranuclear Sn(IV) compound, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)], has site symmetry [Image: see text]. Two O(2−) and two OH(−) anions bridge four Sn(IV) cations to form the tetranuclear compound. The two independent Sn(IV) cations assume SnO(3)C(2) and SnO(2)C(2)Cl distorted trigonal-bipyramidal coordination geometries. Intramolecular O—H⋯Cl hydrogen bonding is present in the structure. One Cl atom of a chlorobenzyl ligand is disordered over two sites with an occupancy ratio of 0.693 (2):0.307 (2). International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971409/ /pubmed/21578215 http://dx.doi.org/10.1107/S1600536809045176 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Qi-Jun Yin, Han-Dong Wen, Li-Yuan Wang, Da-Qi Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title | Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title_full | Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title_fullStr | Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title_full_unstemmed | Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title_short | Dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(IV) |
| title_sort | dichloridooctakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-tetratin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971409/ https://www.ncbi.nlm.nih.gov/pubmed/21578215 http://dx.doi.org/10.1107/S1600536809045176 |
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