1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione

In the title compound, C(23)H(8)F(10)O(2), the three arene rings are twisted one with respect to the other: the two perfluorinated arene rings are tilted to each other by an angle of 60.39 (7)°. They are inclined to the non-fluorinated phenyl unit by 38.85 (7) and 78.74 (7)°. The olefinic double bon...

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Detalles Bibliográficos
Autores principales: Schwarzer, Anke, Weber, Edwin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971416/
https://www.ncbi.nlm.nih.gov/pubmed/21578393
http://dx.doi.org/10.1107/S1600536809041701
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author Schwarzer, Anke
Weber, Edwin
author_facet Schwarzer, Anke
Weber, Edwin
author_sort Schwarzer, Anke
collection PubMed
description In the title compound, C(23)H(8)F(10)O(2), the three arene rings are twisted one with respect to the other: the two perfluorinated arene rings are tilted to each other by an angle of 60.39 (7)°. They are inclined to the non-fluorinated phenyl unit by 38.85 (7) and 78.74 (7)°. The olefinic double bond adopts an E configuration. The carbonyl groups are not in a coplanar alignment with reference to the neighbouring arene rings. The crystal packing features a number of weak C—H⋯F inter­actions, which leads to the formation of a three-dimensional network.
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spelling pubmed-29714162010-12-30 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione Schwarzer, Anke Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(8)F(10)O(2), the three arene rings are twisted one with respect to the other: the two perfluorinated arene rings are tilted to each other by an angle of 60.39 (7)°. They are inclined to the non-fluorinated phenyl unit by 38.85 (7) and 78.74 (7)°. The olefinic double bond adopts an E configuration. The carbonyl groups are not in a coplanar alignment with reference to the neighbouring arene rings. The crystal packing features a number of weak C—H⋯F inter­actions, which leads to the formation of a three-dimensional network. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971416/ /pubmed/21578393 http://dx.doi.org/10.1107/S1600536809041701 Text en © Schwarzer and Weber 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schwarzer, Anke
Weber, Edwin
1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title_full 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title_fullStr 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title_full_unstemmed 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title_short 1,5-Bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
title_sort 1,5-bis(penta­fluoro­phen­yl)-3-phenyl­pent-2-ene-1,5-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971416/
https://www.ncbi.nlm.nih.gov/pubmed/21578393
http://dx.doi.org/10.1107/S1600536809041701
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