Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate

The title compound, [CrCl(2)(CH(3)CN)(2)(C(26)H(36)N(2))]·CH(3)CN, was synthesized by the reaction of CrCl(2)(THF)(2) with N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine in dichloro­methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chl...

Descripción completa

Detalles Bibliográficos
Autores principales: Peitz, Stephan, Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971420/
https://www.ncbi.nlm.nih.gov/pubmed/21578093
http://dx.doi.org/10.1107/S1600536809040094
_version_ 1782190623479037952
author Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peitz, Stephan
collection PubMed
description The title compound, [CrCl(2)(CH(3)CN)(2)(C(26)H(36)N(2))]·CH(3)CN, was synthesized by the reaction of CrCl(2)(THF)(2) with N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine in dichloro­methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetonitrile mol­ecules in a distorted octa­hedral geometry.
format Text
id pubmed-2971420
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29714202010-12-30 Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate Peitz, Stephan Peulecke, Normen Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CrCl(2)(CH(3)CN)(2)(C(26)H(36)N(2))]·CH(3)CN, was synthesized by the reaction of CrCl(2)(THF)(2) with N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine in dichloro­methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetonitrile mol­ecules in a distorted octa­hedral geometry. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971420/ /pubmed/21578093 http://dx.doi.org/10.1107/S1600536809040094 Text en © Peitz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title_full Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title_fullStr Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title_full_unstemmed Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title_short Diacetonitrile[N,N′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
title_sort diacetonitrile[n,n′-bis(2,6-diisopropyl­phenyl)ethane-1,2-diimine]dichloridochromium(ii) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971420/
https://www.ncbi.nlm.nih.gov/pubmed/21578093
http://dx.doi.org/10.1107/S1600536809040094
work_keys_str_mv AT peitzstephan diacetonitrilennbis26diisopropylphenylethane12diiminedichloridochromiumiiacetonitrilesolvate
AT peuleckenormen diacetonitrilennbis26diisopropylphenylethane12diiminedichloridochromiumiiacetonitrilesolvate
AT mullerberndh diacetonitrilennbis26diisopropylphenylethane12diiminedichloridochromiumiiacetonitrilesolvate
AT spannenberganke diacetonitrilennbis26diisopropylphenylethane12diiminedichloridochromiumiiacetonitrilesolvate
AT rosenthaluwe diacetonitrilennbis26diisopropylphenylethane12diiminedichloridochromiumiiacetonitrilesolvate

Ejemplares similares