4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine

The title compound, C(21)H(19)BrN(2)O(2), is an amidine containing electron-donating meth­oxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric mol­ecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3...

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Detalles Bibliográficos
Autores principales: Pal, Amlan K., Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971424/
https://www.ncbi.nlm.nih.gov/pubmed/21578370
http://dx.doi.org/10.1107/S1600536809040112
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author Pal, Amlan K.
Hanan, Garry S.
author_facet Pal, Amlan K.
Hanan, Garry S.
author_sort Pal, Amlan K.
collection PubMed
description The title compound, C(21)H(19)BrN(2)O(2), is an amidine containing electron-donating meth­oxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric mol­ecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) Å] and imine [1.285 (2) Å] characteristics. In the crystal, symmetry-related mol­ecules are linked via a very weak N—H⋯N inter­action, and C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-29714242010-12-30 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine Pal, Amlan K. Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(19)BrN(2)O(2), is an amidine containing electron-donating meth­oxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric mol­ecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) Å] and imine [1.285 (2) Å] characteristics. In the crystal, symmetry-related mol­ecules are linked via a very weak N—H⋯N inter­action, and C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971424/ /pubmed/21578370 http://dx.doi.org/10.1107/S1600536809040112 Text en © Pal and Hanan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pal, Amlan K.
Hanan, Garry S.
4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title_full 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title_fullStr 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title_full_unstemmed 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title_short 4-Bromo-N,N′-bis­(4-methoxy­phen­yl)benzamidine
title_sort 4-bromo-n,n′-bis­(4-methoxy­phen­yl)benzamidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971424/
https://www.ncbi.nlm.nih.gov/pubmed/21578370
http://dx.doi.org/10.1107/S1600536809040112
work_keys_str_mv AT palamlank 4bromonnbis4methoxyphenylbenzamidine
AT hanangarrys 4bromonnbis4methoxyphenylbenzamidine

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