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Tricarbonyl(η(6)-flavone)chromium(0)
In the title compound, [Cr(C(15)H(10)O(2))(CO)(3)], the Cr(CO)(3) unit exhibits a three-legged piano-stool conformation. The chromium metal centre is coordinated by the phenyl ring of the flavone ligand [Cr—(phenyl centroid) distance = 1.709 (1) Å]. The ligand is approximately planar, the dihedral a...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971426/ https://www.ncbi.nlm.nih.gov/pubmed/21578102 http://dx.doi.org/10.1107/S1600536809040525 |
| Sumario: | In the title compound, [Cr(C(15)H(10)O(2))(CO)(3)], the Cr(CO)(3) unit exhibits a three-legged piano-stool conformation. The chromium metal centre is coordinated by the phenyl ring of the flavone ligand [Cr—(phenyl centroid) distance = 1.709 (1) Å]. The ligand is approximately planar, the dihedral angles between the γ-pyrone ring and the phenyl ring and between the γ-pyrone and the phenylene ring being 2.91 (5) and 3.90 (5)°, respectively. The molecular packing shows π–π stacking between the flavone ligands of neighbouring molecules. |
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