Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)

In the title complex mol­ecule, [CdBr(2)(C(10)H(8)N(2))(2)], the Cd(II) ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2′-bipyridine ligands in a distorted octa­hedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands...

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Detalles Bibliográficos
Autor principal: Zhang, Bi-Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971436/
https://www.ncbi.nlm.nih.gov/pubmed/21578151
http://dx.doi.org/10.1107/S1600536809042597
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author Zhang, Bi-Song
author_facet Zhang, Bi-Song
author_sort Zhang, Bi-Song
collection PubMed
description In the title complex mol­ecule, [CdBr(2)(C(10)H(8)N(2))(2)], the Cd(II) ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2′-bipyridine ligands in a distorted octa­hedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)°. In the crystal packing, π–π stacking inter­actions [centroid–centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex mol­ecules into chains running parallel to the b axis. The chains are further connected by inter­molecular C—H⋯Br hydrogen bonds into a three-dimensional network.
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spelling pubmed-29714362010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II) Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex mol­ecule, [CdBr(2)(C(10)H(8)N(2))(2)], the Cd(II) ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2′-bipyridine ligands in a distorted octa­hedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)°. In the crystal packing, π–π stacking inter­actions [centroid–centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex mol­ecules into chains running parallel to the b axis. The chains are further connected by inter­molecular C—H⋯Br hydrogen bonds into a three-dimensional network. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971436/ /pubmed/21578151 http://dx.doi.org/10.1107/S1600536809042597 Text en © Bi-Song Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Bi-Song
Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title_full Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title_fullStr Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title_full_unstemmed Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title_short Bis(2,2′-bipyridine-κ(2) N,N′)dibromido­cadmium(II)
title_sort bis(2,2′-bipyridine-κ(2) n,n′)dibromido­cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971436/
https://www.ncbi.nlm.nih.gov/pubmed/21578151
http://dx.doi.org/10.1107/S1600536809042597
work_keys_str_mv AT zhangbisong bis22bipyridinek2nndibromidocadmiumii

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