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Hexaaquamagnesium(II) bis{[N-(4-methoxy-2-oxidobenzylidene)glycylglycinato(3−)]cuprate(II)} hexahydrate
In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetradentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971438/ https://www.ncbi.nlm.nih.gov/pubmed/21578107 http://dx.doi.org/10.1107/S1600536809040872 |
Sumario: | In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetradentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and one carboxylate O atom. The Mg(II) center, which sits on an inversion center, is coordinated by six aqua ligands and exhibits a slightly distorted octahedral conformation. The asymmetric unit consists of an [N-(4-methoxy-2-oxidobenzylidene)glycylglycinato]cuprate(II) anion, one half of an [Mg(H(2)O)(6)](2+) cation and three free water molecules. The cations and anions form columns by O—H⋯O hydrogen bonds. |
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