Cargando…

Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate

In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetra­dentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiang, Jiaxun, Lu, Yao, Yuan, Limin, Liu, Wenlong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971438/
https://www.ncbi.nlm.nih.gov/pubmed/21578107
http://dx.doi.org/10.1107/S1600536809040872
Descripción
Sumario:In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetra­dentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and one carboxyl­ate O atom. The Mg(II) center, which sits on an inversion center, is coordinated by six aqua ligands and exhibits a slightly distorted octa­hedral conformation. The asymmetric unit consists of an [N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato]cuprate(II) anion, one half of an [Mg(H(2)O)(6)](2+) cation and three free water mol­ecules. The cations and anions form columns by O—H⋯O hydrogen bonds.