Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate

In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetra­dentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and...

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Detalles Bibliográficos
Autores principales: Jiang, Jiaxun, Lu, Yao, Yuan, Limin, Liu, Wenlong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971438/
https://www.ncbi.nlm.nih.gov/pubmed/21578107
http://dx.doi.org/10.1107/S1600536809040872
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author Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
author_facet Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
author_sort Jiang, Jiaxun
collection PubMed
description In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetra­dentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and one carboxyl­ate O atom. The Mg(II) center, which sits on an inversion center, is coordinated by six aqua ligands and exhibits a slightly distorted octa­hedral conformation. The asymmetric unit consists of an [N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato]cuprate(II) anion, one half of an [Mg(H(2)O)(6)](2+) cation and three free water mol­ecules. The cations and anions form columns by O—H⋯O hydrogen bonds.
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spelling pubmed-29714382010-12-30 Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate Jiang, Jiaxun Lu, Yao Yuan, Limin Liu, Wenlong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mg(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Cu(II) atoms lie at the center of the square plane of triple negatively charged O,N,N′,O′-tetra­dentate Schiff base ligands, which are coordinated by one phenolate O atom, one imine N atom, one deprotonated amide N atom and one carboxyl­ate O atom. The Mg(II) center, which sits on an inversion center, is coordinated by six aqua ligands and exhibits a slightly distorted octa­hedral conformation. The asymmetric unit consists of an [N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato]cuprate(II) anion, one half of an [Mg(H(2)O)(6)](2+) cation and three free water mol­ecules. The cations and anions form columns by O—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971438/ /pubmed/21578107 http://dx.doi.org/10.1107/S1600536809040872 Text en © Jiang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Jiaxun
Lu, Yao
Yuan, Limin
Liu, Wenlong
Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title_full Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title_fullStr Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title_full_unstemmed Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title_short Hexaaqua­magnesium(II) bis­{[N-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(II)} hexa­hydrate
title_sort hexaaqua­magnesium(ii) bis­{[n-(4-meth­oxy-2-oxidobenzyl­idene)glycyl­glycinato(3−)]cuprate(ii)} hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971438/
https://www.ncbi.nlm.nih.gov/pubmed/21578107
http://dx.doi.org/10.1107/S1600536809040872
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AT yuanlimin hexaaquamagnesiumiibisn4methoxy2oxidobenzylideneglycylglycinato3cuprateiihexahydrate
AT liuwenlong hexaaquamagnesiumiibisn4methoxy2oxidobenzylideneglycylglycinato3cuprateiihexahydrate

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