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[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)

In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical mol­ecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intra­molecular Au⋯O contacts [2.99...

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Detalles Bibliográficos
Autores principales: Ho, Soo Yei, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/
https://www.ncbi.nlm.nih.gov/pubmed/21578176
http://dx.doi.org/10.1107/S1600536809043499
Descripción
Sumario:In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical mol­ecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intra­molecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supra­molecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π inter­actions are evident in the crystal structure. These are connected into layers via weak inter­molecular C—H⋯O inter­actions involving the nitro-group O atoms.