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[(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I)
In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical molecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intramolecular Au⋯O contacts [2.99...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/ https://www.ncbi.nlm.nih.gov/pubmed/21578176 http://dx.doi.org/10.1107/S1600536809043499 |
Sumario: | In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical molecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intramolecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supramolecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π interactions are evident in the crystal structure. These are connected into layers via weak intermolecular C—H⋯O interactions involving the nitro-group O atoms. |
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