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[(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I)
In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical molecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intramolecular Au⋯O contacts [2.99...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/ https://www.ncbi.nlm.nih.gov/pubmed/21578176 http://dx.doi.org/10.1107/S1600536809043499 |
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author | Ho, Soo Yei Tiekink, Edward R. T. |
author_facet | Ho, Soo Yei Tiekink, Edward R. T. |
author_sort | Ho, Soo Yei |
collection | PubMed |
description | In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical molecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intramolecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supramolecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π interactions are evident in the crystal structure. These are connected into layers via weak intermolecular C—H⋯O interactions involving the nitro-group O atoms. |
format | Text |
id | pubmed-2971440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29714402010-12-30 [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) Ho, Soo Yei Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical molecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intramolecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supramolecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π interactions are evident in the crystal structure. These are connected into layers via weak intermolecular C—H⋯O interactions involving the nitro-group O atoms. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971440/ /pubmed/21578176 http://dx.doi.org/10.1107/S1600536809043499 Text en © Ho and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ho, Soo Yei Tiekink, Edward R. T. [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title | [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title_full | [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title_fullStr | [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title_full_unstemmed | [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title_short | [(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](triethylphosphine-κP)gold(I) |
title_sort | [(z)-o-ethyl n-(4-nitrophenyl)thiocarbamato-κs](triethylphosphine-κp)gold(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/ https://www.ncbi.nlm.nih.gov/pubmed/21578176 http://dx.doi.org/10.1107/S1600536809043499 |
work_keys_str_mv | AT hosooyei zoethyln4nitrophenylthiocarbamatokstriethylphosphinekpgoldi AT tiekinkedwardrt zoethyln4nitrophenylthiocarbamatokstriethylphosphinekpgoldi |