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[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)

In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical mol­ecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intra­molecular Au⋯O contacts [2.99...

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Detalles Bibliográficos
Autores principales: Ho, Soo Yei, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/
https://www.ncbi.nlm.nih.gov/pubmed/21578176
http://dx.doi.org/10.1107/S1600536809043499
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author Ho, Soo Yei
Tiekink, Edward R. T.
author_facet Ho, Soo Yei
Tiekink, Edward R. T.
author_sort Ho, Soo Yei
collection PubMed
description In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical mol­ecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intra­molecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supra­molecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π inter­actions are evident in the crystal structure. These are connected into layers via weak inter­molecular C—H⋯O inter­actions involving the nitro-group O atoms.
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spelling pubmed-29714402010-12-30 [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I) Ho, Soo Yei Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(6)H(15)P)], two virtually identical mol­ecules comprise the asymmetric unit. These are connected by Au⋯Au [3.6796 (4) Å] and Au⋯S [3.6325 (18) and 3.5471 (18) Å] contacts, forming a dimeric aggregate. The presence of intra­molecular Au⋯O contacts [2.993 (5) and 2.957 (5) Å] is responsible for the slight deviations from the ideal linear coordination environments about the Au(I) ions. The conformation about the central C=N double bond is Z. Supra­molecular chains sustained by π–π [3.573 (4) Å] and C—H⋯π inter­actions are evident in the crystal structure. These are connected into layers via weak inter­molecular C—H⋯O inter­actions involving the nitro-group O atoms. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971440/ /pubmed/21578176 http://dx.doi.org/10.1107/S1600536809043499 Text en © Ho and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ho, Soo Yei
Tiekink, Edward R. T.
[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title_full [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title_short [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triethyl­phosphine-κP)gold(I)
title_sort [(z)-o-ethyl n-(4-nitro­phen­yl)thio­carbamato-κs](triethyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971440/
https://www.ncbi.nlm.nih.gov/pubmed/21578176
http://dx.doi.org/10.1107/S1600536809043499
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