trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)

The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis­(2-meth...

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Detalles Bibliográficos
Autores principales: van Blerk, Charmaine, Holzapfel, Cedric W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971441/
https://www.ncbi.nlm.nih.gov/pubmed/21578097
http://dx.doi.org/10.1107/S1600536809040744
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author van Blerk, Charmaine
Holzapfel, Cedric W.
author_facet van Blerk, Charmaine
Holzapfel, Cedric W.
author_sort van Blerk, Charmaine
collection PubMed
description The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis­(2-methoxy­phen­yl)phenyl­phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.
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spelling pubmed-29714412010-12-30 trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II) van Blerk, Charmaine Holzapfel, Cedric W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis­(2-methoxy­phen­yl)phenyl­phosphine ligand. The trans arrangement of ligands is also imposed by symmetry. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971441/ /pubmed/21578097 http://dx.doi.org/10.1107/S1600536809040744 Text en © Blerk and Holzapfel 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van Blerk, Charmaine
Holzapfel, Cedric W.
trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title_full trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title_fullStr trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title_full_unstemmed trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title_short trans-Bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κP]dichloridopalladium(II)
title_sort trans-bis[bis­(2-methoxy­phen­yl)phenyl­phosphine-κp]dichloridopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971441/
https://www.ncbi.nlm.nih.gov/pubmed/21578097
http://dx.doi.org/10.1107/S1600536809040744
work_keys_str_mv AT vanblerkcharmaine transbisbis2methoxyphenylphenylphosphinekpdichloridopalladiumii
AT holzapfelcedricw transbisbis2methoxyphenylphenylphosphinekpdichloridopalladiumii

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