Cargando…

5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate

In the title compound (alternatively called 4′,5,7-trimethoxy­flavone methanol solvate hydrate), C(18)H(16)O(5)·CH(3)OH·H(2)O, the flavone mol­ecule is almost planar, the inter­planar angle between the planes of the benzopyran-4-one group and the attached benzene ring being 4.69 (9)°. In the crystal...

Descripción completa

Detalles Bibliográficos
Autores principales: Aree, Thammarat, Sabphon, Chalisa, Sawasdee, Pattara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971445/
https://www.ncbi.nlm.nih.gov/pubmed/21578297
http://dx.doi.org/10.1107/S1600536809040513
_version_ 1782190629658296320
author Aree, Thammarat
Sabphon, Chalisa
Sawasdee, Pattara
author_facet Aree, Thammarat
Sabphon, Chalisa
Sawasdee, Pattara
author_sort Aree, Thammarat
collection PubMed
description In the title compound (alternatively called 4′,5,7-trimethoxy­flavone methanol solvate hydrate), C(18)H(16)O(5)·CH(3)OH·H(2)O, the flavone mol­ecule is almost planar, the inter­planar angle between the planes of the benzopyran-4-one group and the attached benzene ring being 4.69 (9)°. In the crystal, the flavone mol­ecule makes inter­molecular C—H⋯O hydrogen bonds to adjacent inversion-related flavone mol­ecules, generating R (2) (2)(8) and R (2) (2)(14) rings and an infinite ribbon. The inversion-related ribbons are stabilized through the inter­stitial water and methanol mol­ecules via inter­molecular O—H⋯O hydrogen bonds, generating R (4) (2)(8) and R (2) (1)(6) rings and C (2) (2)(4) chains, and are further sustained by π–π inter­actions with an inter­planar spacing of 3.365 (2)Å.
format Text
id pubmed-2971445
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29714452010-12-30 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate Aree, Thammarat Sabphon, Chalisa Sawasdee, Pattara Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (alternatively called 4′,5,7-trimethoxy­flavone methanol solvate hydrate), C(18)H(16)O(5)·CH(3)OH·H(2)O, the flavone mol­ecule is almost planar, the inter­planar angle between the planes of the benzopyran-4-one group and the attached benzene ring being 4.69 (9)°. In the crystal, the flavone mol­ecule makes inter­molecular C—H⋯O hydrogen bonds to adjacent inversion-related flavone mol­ecules, generating R (2) (2)(8) and R (2) (2)(14) rings and an infinite ribbon. The inversion-related ribbons are stabilized through the inter­stitial water and methanol mol­ecules via inter­molecular O—H⋯O hydrogen bonds, generating R (4) (2)(8) and R (2) (1)(6) rings and C (2) (2)(4) chains, and are further sustained by π–π inter­actions with an inter­planar spacing of 3.365 (2)Å. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971445/ /pubmed/21578297 http://dx.doi.org/10.1107/S1600536809040513 Text en © Aree et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aree, Thammarat
Sabphon, Chalisa
Sawasdee, Pattara
5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title_full 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title_fullStr 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title_full_unstemmed 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title_short 5,7-Dimeth­oxy-2-(4-methoxy­phen­yl)-4H-1-benzopyran-4-one methanol solvate monohydrate
title_sort 5,7-dimeth­oxy-2-(4-methoxy­phen­yl)-4h-1-benzopyran-4-one methanol solvate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971445/
https://www.ncbi.nlm.nih.gov/pubmed/21578297
http://dx.doi.org/10.1107/S1600536809040513
work_keys_str_mv AT areethammarat 57dimethoxy24methoxyphenyl4h1benzopyran4onemethanolsolvatemonohydrate
AT sabphonchalisa 57dimethoxy24methoxyphenyl4h1benzopyran4onemethanolsolvatemonohydrate
AT sawasdeepattara 57dimethoxy24methoxyphenyl4h1benzopyran4onemethanolsolvatemonohydrate