Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study

The title compound, penta­iron tripraseodymium dodeca­oxide (PrIG), has an iron garnet structure. There are two Fe site symmetries. One of the Fe atoms is coordinated by six O atoms, forming a slightly distorted octa­hedron, and has [Image: see text] site symmetry. The other Fe atom is coordinated b...

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Autores principales: Komori, Takashi, Sakakura, Terutoshi, Takenaka, Yasuyuki, Tanaka, Kiyoaki, Okuda, Takashi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971448/
https://www.ncbi.nlm.nih.gov/pubmed/21578032
http://dx.doi.org/10.1107/S1600536809038100
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author Komori, Takashi
Sakakura, Terutoshi
Takenaka, Yasuyuki
Tanaka, Kiyoaki
Okuda, Takashi
author_facet Komori, Takashi
Sakakura, Terutoshi
Takenaka, Yasuyuki
Tanaka, Kiyoaki
Okuda, Takashi
author_sort Komori, Takashi
collection PubMed
description The title compound, penta­iron tripraseodymium dodeca­oxide (PrIG), has an iron garnet structure. There are two Fe site symmetries. One of the Fe atoms is coordinated by six O atoms, forming a slightly distorted octa­hedron, and has [Image: see text] site symmetry. The other Fe atom is coordinated by four O atoms, forming a slightly distorted tetra­hedron, and has [Image: see text] site symmetry. FeO(6) octa­hedra and FeO(4) tetra­hedra are linked together by corners. The Pr atom is coordinated by eight O atoms, forming a distorted dodeca­hedron, and has 222 site symmetry. The O atoms occupy the general positions.
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spelling pubmed-29714482010-12-30 Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study Komori, Takashi Sakakura, Terutoshi Takenaka, Yasuyuki Tanaka, Kiyoaki Okuda, Takashi Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, penta­iron tripraseodymium dodeca­oxide (PrIG), has an iron garnet structure. There are two Fe site symmetries. One of the Fe atoms is coordinated by six O atoms, forming a slightly distorted octa­hedron, and has [Image: see text] site symmetry. The other Fe atom is coordinated by four O atoms, forming a slightly distorted tetra­hedron, and has [Image: see text] site symmetry. FeO(6) octa­hedra and FeO(4) tetra­hedra are linked together by corners. The Pr atom is coordinated by eight O atoms, forming a distorted dodeca­hedron, and has 222 site symmetry. The O atoms occupy the general positions. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971448/ /pubmed/21578032 http://dx.doi.org/10.1107/S1600536809038100 Text en © Komori et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Komori, Takashi
Sakakura, Terutoshi
Takenaka, Yasuyuki
Tanaka, Kiyoaki
Okuda, Takashi
Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title_full Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title_fullStr Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title_full_unstemmed Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title_short Tripraseodymium penta­iron(III) dodeca­oxide, Pr(3)Fe(5)O(12): a synchrotron radiation study
title_sort tripraseodymium penta­iron(iii) dodeca­oxide, pr(3)fe(5)o(12): a synchrotron radiation study
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971448/
https://www.ncbi.nlm.nih.gov/pubmed/21578032
http://dx.doi.org/10.1107/S1600536809038100
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