[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate

An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S—Au—P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra­molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized...

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Detalles Bibliográficos
Autores principales: Ho, Soo Yei, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971450/
https://www.ncbi.nlm.nih.gov/pubmed/21578192
http://dx.doi.org/10.1107/S1600536809043876
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author Ho, Soo Yei
Tiekink, Edward R. T.
author_facet Ho, Soo Yei
Tiekink, Edward R. T.
author_sort Ho, Soo Yei
collection PubMed
description An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S—Au—P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra­molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C—H⋯S, C—H⋯N and C—H⋯O contacts.
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spelling pubmed-29714502010-12-30 [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate Ho, Soo Yei Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S—Au—P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra­molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C—H⋯S, C—H⋯N and C—H⋯O contacts. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971450/ /pubmed/21578192 http://dx.doi.org/10.1107/S1600536809043876 Text en © Ho and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ho, Soo Yei
Tiekink, Edward R. T.
[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title_full [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title_fullStr [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title_full_unstemmed [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title_short [(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate
title_sort [(z)-o-ethyl n-(4-nitro­phen­yl)thio­carbamato-κs](triphenyl­phosphine-κp)gold(i) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971450/
https://www.ncbi.nlm.nih.gov/pubmed/21578192
http://dx.doi.org/10.1107/S1600536809043876
work_keys_str_mv AT hosooyei zoethyln4nitrophenylthiocarbamatokstriphenylphosphinekpgoldidichloromethanesolvate
AT tiekinkedwardrt zoethyln4nitrophenylthiocarbamatokstriphenylphosphinekpgoldidichloromethanesolvate

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