N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline

In the title mol­ecule, C(20)H(19)Cl(2)N(3)OS, the dihedral angle between the two benzene rings is 79.3 (7)°. The 4-chloro-6-methoxy­pyrimidine group is rotationally disordered over two sites by approximately 180°, the ratio of the refined occupancies being 0.6772 (15):0.3228 (15). Both disorder com...

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Detalles Bibliográficos
Autores principales: Fu, Weijun, Zhu, Mei, Hong, Dongfeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971454/
https://www.ncbi.nlm.nih.gov/pubmed/21578352
http://dx.doi.org/10.1107/S1600536809041026
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author Fu, Weijun
Zhu, Mei
Hong, Dongfeng
author_facet Fu, Weijun
Zhu, Mei
Hong, Dongfeng
author_sort Fu, Weijun
collection PubMed
description In the title mol­ecule, C(20)H(19)Cl(2)N(3)OS, the dihedral angle between the two benzene rings is 79.3 (7)°. The 4-chloro-6-methoxy­pyrimidine group is rotationally disordered over two sites by approximately 180°, the ratio of the refined occupancies being 0.6772 (15):0.3228 (15). Both disorder components of disorder are involved in intra­molecular N—H⋯N hydrogen bonds.
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spelling pubmed-29714542010-12-30 N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline Fu, Weijun Zhu, Mei Hong, Dongfeng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(20)H(19)Cl(2)N(3)OS, the dihedral angle between the two benzene rings is 79.3 (7)°. The 4-chloro-6-methoxy­pyrimidine group is rotationally disordered over two sites by approximately 180°, the ratio of the refined occupancies being 0.6772 (15):0.3228 (15). Both disorder components of disorder are involved in intra­molecular N—H⋯N hydrogen bonds. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971454/ /pubmed/21578352 http://dx.doi.org/10.1107/S1600536809041026 Text en © Fu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fu, Weijun
Zhu, Mei
Hong, Dongfeng
N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title_full N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title_fullStr N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title_full_unstemmed N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title_short N-[2-Chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
title_sort n-[2-chloro-6-(4-chloro-6-methoxy­pyrimidin-2-ylsulfan­yl)benz­yl]-3,4-dimethyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971454/
https://www.ncbi.nlm.nih.gov/pubmed/21578352
http://dx.doi.org/10.1107/S1600536809041026
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AT zhumei n2chloro64chloro6methoxypyrimidin2ylsulfanylbenzyl34dimethylaniline
AT hongdongfeng n2chloro64chloro6methoxypyrimidin2ylsulfanylbenzyl34dimethylaniline

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