(Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile

The asymmetric unit of the title compound, C(11)H(9)N(3)O, contains two independent and nearly identical mol­ecules (A and B). Mol­ecule A can be transformed to B using a rotation of approximately 85° around the [111] direction. Each A mol­ecule is connected to three B mol­ecules via N—H⋯N and N—H⋯O...

Descripción completa

Detalles Bibliográficos
Autores principales: Schollmeyer, Dieter, Ferenc, Dorota, Opatz, Till
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971748/
https://www.ncbi.nlm.nih.gov/pubmed/21578761
http://dx.doi.org/10.1107/S1600536809045681
_version_ 1782190658628354048
author Schollmeyer, Dieter
Ferenc, Dorota
Opatz, Till
author_facet Schollmeyer, Dieter
Ferenc, Dorota
Opatz, Till
author_sort Schollmeyer, Dieter
collection PubMed
description The asymmetric unit of the title compound, C(11)H(9)N(3)O, contains two independent and nearly identical mol­ecules (A and B). Mol­ecule A can be transformed to B using a rotation of approximately 85° around the [111] direction. Each A mol­ecule is connected to three B mol­ecules via N—H⋯N and N—H⋯O hydrogen bonds and vice versa. Centrosymmetric­ally related mol­ecules of the same residue form π–π inter­actions with centroid–centroid distances of 4.326 (1) and 3.826 (1) Å for the benzene rings of mol­ecules A and B, respectively.
format Text
id pubmed-2971748
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29717482010-12-30 (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile Schollmeyer, Dieter Ferenc, Dorota Opatz, Till Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(9)N(3)O, contains two independent and nearly identical mol­ecules (A and B). Mol­ecule A can be transformed to B using a rotation of approximately 85° around the [111] direction. Each A mol­ecule is connected to three B mol­ecules via N—H⋯N and N—H⋯O hydrogen bonds and vice versa. Centrosymmetric­ally related mol­ecules of the same residue form π–π inter­actions with centroid–centroid distances of 4.326 (1) and 3.826 (1) Å for the benzene rings of mol­ecules A and B, respectively. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971748/ /pubmed/21578761 http://dx.doi.org/10.1107/S1600536809045681 Text en © Schollmeyer et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schollmeyer, Dieter
Ferenc, Dorota
Opatz, Till
(Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title_full (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title_fullStr (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title_full_unstemmed (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title_short (Z)-Amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
title_sort (z)-amino­(2-methyl-3-oxoisoindolin-1-yl­idene)acetonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971748/
https://www.ncbi.nlm.nih.gov/pubmed/21578761
http://dx.doi.org/10.1107/S1600536809045681
work_keys_str_mv AT schollmeyerdieter zamino2methyl3oxoisoindolin1ylideneacetonitrile
AT ferencdorota zamino2methyl3oxoisoindolin1ylideneacetonitrile
AT opatztill zamino2methyl3oxoisoindolin1ylideneacetonitrile

Ejemplares similares