Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)

In the centrosymmetric dinuclear Cu(II) title complex, [Cu(2)(C(18)H(16)Cl(4)N(2)O(2))(2)], the Cu(II) atom adopts a square-pyramidal geometry with a tetra­dentate ligand in the basal plane. The apical site is occupied by a phenolate O atom from an adjacent ligand, forming a dimer. The mol­ecular st...

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Detalles Bibliográficos
Autores principales: Kubono, Koji, Noshita, Chisato, Tani, Keita, Yokoi, Kunihiko
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971750/
https://www.ncbi.nlm.nih.gov/pubmed/21578691
http://dx.doi.org/10.1107/S1600536809049800
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author Kubono, Koji
Noshita, Chisato
Tani, Keita
Yokoi, Kunihiko
author_facet Kubono, Koji
Noshita, Chisato
Tani, Keita
Yokoi, Kunihiko
author_sort Kubono, Koji
collection PubMed
description In the centrosymmetric dinuclear Cu(II) title complex, [Cu(2)(C(18)H(16)Cl(4)N(2)O(2))(2)], the Cu(II) atom adopts a square-pyramidal geometry with a tetra­dentate ligand in the basal plane. The apical site is occupied by a phenolate O atom from an adjacent ligand, forming a dimer. The mol­ecular structure is stabilized by intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonds.
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spelling pubmed-29717502010-12-30 Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II) Kubono, Koji Noshita, Chisato Tani, Keita Yokoi, Kunihiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear Cu(II) title complex, [Cu(2)(C(18)H(16)Cl(4)N(2)O(2))(2)], the Cu(II) atom adopts a square-pyramidal geometry with a tetra­dentate ligand in the basal plane. The apical site is occupied by a phenolate O atom from an adjacent ligand, forming a dimer. The mol­ecular structure is stabilized by intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971750/ /pubmed/21578691 http://dx.doi.org/10.1107/S1600536809049800 Text en © Kubono et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kubono, Koji
Noshita, Chisato
Tani, Keita
Yokoi, Kunihiko
Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title_full Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title_fullStr Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title_full_unstemmed Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title_short Bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(II)
title_sort bis[μ-4,4′,6,6′-tetra­chloro-2,2′-(piperazine-1,4-diyldimethyl­ene)diphenolato]dicopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971750/
https://www.ncbi.nlm.nih.gov/pubmed/21578691
http://dx.doi.org/10.1107/S1600536809049800
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