Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)

The title compound, (C(6)H(9)N(2))(2)[CuCl(4)], contains a distorted tetra­hedral [CuCl(4)](2−) anion and two protonated amino­pyridinium cations. The geometries of the protonated amino­pyridinium cations reveal amine–imine tautomerism. The crystal packing is influenced by N—H⋯Cl and C—H⋯Cl hydrogen...

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Detalles Bibliográficos
Autores principales: Gong, Jiang, Chen, Gang, Ni, Shi-Feng, Zhang, Yong-Yao, Wang, Hai-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971753/
https://www.ncbi.nlm.nih.gov/pubmed/21578672
http://dx.doi.org/10.1107/S160053680904923X
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author Gong, Jiang
Chen, Gang
Ni, Shi-Feng
Zhang, Yong-Yao
Wang, Hai-Bin
author_facet Gong, Jiang
Chen, Gang
Ni, Shi-Feng
Zhang, Yong-Yao
Wang, Hai-Bin
author_sort Gong, Jiang
collection PubMed
description The title compound, (C(6)H(9)N(2))(2)[CuCl(4)], contains a distorted tetra­hedral [CuCl(4)](2−) anion and two protonated amino­pyridinium cations. The geometries of the protonated amino­pyridinium cations reveal amine–imine tautomerism. The crystal packing is influenced by N—H⋯Cl and C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.635 (4) and 3.642 (4)°].
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spelling pubmed-29717532010-12-30 Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II) Gong, Jiang Chen, Gang Ni, Shi-Feng Zhang, Yong-Yao Wang, Hai-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(9)N(2))(2)[CuCl(4)], contains a distorted tetra­hedral [CuCl(4)](2−) anion and two protonated amino­pyridinium cations. The geometries of the protonated amino­pyridinium cations reveal amine–imine tautomerism. The crystal packing is influenced by N—H⋯Cl and C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.635 (4) and 3.642 (4)°]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971753/ /pubmed/21578672 http://dx.doi.org/10.1107/S160053680904923X Text en © Gong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gong, Jiang
Chen, Gang
Ni, Shi-Feng
Zhang, Yong-Yao
Wang, Hai-Bin
Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title_full Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title_fullStr Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title_full_unstemmed Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title_short Bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(II)
title_sort bis(2-amino-6-methyl­pyridinium) tetra­chloridocuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971753/
https://www.ncbi.nlm.nih.gov/pubmed/21578672
http://dx.doi.org/10.1107/S160053680904923X
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