Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride

In the crystal structure of the title compound, [Co(C(7)H(6)N(2))(2)(H(2)O)(4)]Cl(2), the Co(II) cation lies on an inversion center and is coordinated by two 2-amino­benzonitrile ligands and four water mol­ecules in a distorted octa­hedral geometry. The Cl(−) counter-anion links with the complex cat...

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Detalles Bibliográficos
Autores principales: Ru, Zong-Ling, Wang, Guo-Xi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971755/
https://www.ncbi.nlm.nih.gov/pubmed/21578693
http://dx.doi.org/10.1107/S1600536809050272
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author Ru, Zong-Ling
Wang, Guo-Xi
author_facet Ru, Zong-Ling
Wang, Guo-Xi
author_sort Ru, Zong-Ling
collection PubMed
description In the crystal structure of the title compound, [Co(C(7)H(6)N(2))(2)(H(2)O)(4)]Cl(2), the Co(II) cation lies on an inversion center and is coordinated by two 2-amino­benzonitrile ligands and four water mol­ecules in a distorted octa­hedral geometry. The Cl(−) counter-anion links with the complex cations via O—H⋯Cl and N—H⋯Cl hydrogen bonding. Inter­molecular O—H⋯N hydrogen bonding links the complex cations, forming supra­molecular chains running along the b axis.
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spelling pubmed-29717552010-12-30 Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride Ru, Zong-Ling Wang, Guo-Xi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(C(7)H(6)N(2))(2)(H(2)O)(4)]Cl(2), the Co(II) cation lies on an inversion center and is coordinated by two 2-amino­benzonitrile ligands and four water mol­ecules in a distorted octa­hedral geometry. The Cl(−) counter-anion links with the complex cations via O—H⋯Cl and N—H⋯Cl hydrogen bonding. Inter­molecular O—H⋯N hydrogen bonding links the complex cations, forming supra­molecular chains running along the b axis. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971755/ /pubmed/21578693 http://dx.doi.org/10.1107/S1600536809050272 Text en © Ru and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ru, Zong-Ling
Wang, Guo-Xi
Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title_full Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title_fullStr Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title_full_unstemmed Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title_short Bis(2-amino­benzonitrile)tetra­aqua­cobalt(II) dichloride
title_sort bis(2-amino­benzonitrile)tetra­aqua­cobalt(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971755/
https://www.ncbi.nlm.nih.gov/pubmed/21578693
http://dx.doi.org/10.1107/S1600536809050272
work_keys_str_mv AT ruzongling bis2aminobenzonitriletetraaquacobaltiidichloride
AT wangguoxi bis2aminobenzonitriletetraaquacobaltiidichloride

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