[μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}

In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S—Au—P = 178.17 (8) Å] is due to an intra­molecular Au⋯O contact [3.079 (4) Å]. In...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971759/
https://www.ncbi.nlm.nih.gov/pubmed/21578625
http://dx.doi.org/10.1107/S1600536809047898
Descripción
Sumario:In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S—Au—P = 178.17 (8) Å] is due to an intra­molecular Au⋯O contact [3.079 (4) Å]. In the crystal, supra­molecular chains mediated by C—H⋯N inter­actions are formed, which run parallel to [001].

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