[μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}

In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S—Au—P = 178.17 (8) Å] is due to an intra­molecular Au⋯O contact [3.079 (4) Å]. In...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971759/
https://www.ncbi.nlm.nih.gov/pubmed/21578625
http://dx.doi.org/10.1107/S1600536809047898
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S—Au—P = 178.17 (8) Å] is due to an intra­molecular Au⋯O contact [3.079 (4) Å]. In the crystal, supra­molecular chains mediated by C—H⋯N inter­actions are formed, which run parallel to [001].
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spelling pubmed-29717592010-12-30 [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)} Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S—Au—P = 178.17 (8) Å] is due to an intra­molecular Au⋯O contact [3.079 (4) Å]. In the crystal, supra­molecular chains mediated by C—H⋯N inter­actions are formed, which run parallel to [001]. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2971759/ /pubmed/21578625 http://dx.doi.org/10.1107/S1600536809047898 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title_full [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title_fullStr [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title_full_unstemmed [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title_short [μ-1,1′-Bis(diphenyl­phosphino)ferrocene-κ(2) P:P′]bis­{[(Z)-O-isopropyl-N-(4-methyl­phen­yl)thio­carbamato-κS]gold(I)}
title_sort [μ-1,1′-bis(diphenyl­phosphino)ferrocene-κ(2) p:p′]bis­{[(z)-o-isopropyl-n-(4-methyl­phen­yl)thio­carbamato-κs]gold(i)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971759/
https://www.ncbi.nlm.nih.gov/pubmed/21578625
http://dx.doi.org/10.1107/S1600536809047898
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AT tiekinkedwardrt m11bisdiphenylphosphinoferrocenek2ppbiszoisopropyln4methylphenylthiocarbamatoksgoldi

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