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Tetraaquadiazidocobalt(II) 4,4′-dicarboxylato-1,1′-ethylenedipyridinium dihydrate
In the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4)·2H(2)O, the metal complex molecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octahedral geometry. The zwitterionic organic molecule is also centrosymmetric. In...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971761/ https://www.ncbi.nlm.nih.gov/pubmed/21578688 http://dx.doi.org/10.1107/S1600536809049848 |
Sumario: | In the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4)·2H(2)O, the metal complex molecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octahedral geometry. The zwitterionic organic molecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O—H⋯O hydrogen bonds. Further O—H⋯O and O—H⋯N interactions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio. |
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