Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate

In the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4)·2H(2)O, the metal complex mol­ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric. In...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Kun, Wang, Yan-Qin, Zhang, Jian-Yong, Gao, En-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971761/
https://www.ncbi.nlm.nih.gov/pubmed/21578688
http://dx.doi.org/10.1107/S1600536809049848
_version_ 1782190661828608000
author Wang, Kun
Wang, Yan-Qin
Zhang, Jian-Yong
Gao, En-Qing
author_facet Wang, Kun
Wang, Yan-Qin
Zhang, Jian-Yong
Gao, En-Qing
author_sort Wang, Kun
collection PubMed
description In the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4)·2H(2)O, the metal complex mol­ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O—H⋯O hydrogen bonds. Further O—H⋯O and O—H⋯N inter­actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.
format Text
id pubmed-2971761
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29717612010-12-30 Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate Wang, Kun Wang, Yan-Qin Zhang, Jian-Yong Gao, En-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(N(3))(2)(H(2)O)(4)]·C(14)H(12)N(2)O(4)·2H(2)O, the metal complex mol­ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O—H⋯O hydrogen bonds. Further O—H⋯O and O—H⋯N inter­actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971761/ /pubmed/21578688 http://dx.doi.org/10.1107/S1600536809049848 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Kun
Wang, Yan-Qin
Zhang, Jian-Yong
Gao, En-Qing
Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title_full Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title_fullStr Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title_full_unstemmed Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title_short Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
title_sort tetra­aqua­diazido­cobalt(ii) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971761/
https://www.ncbi.nlm.nih.gov/pubmed/21578688
http://dx.doi.org/10.1107/S1600536809049848
work_keys_str_mv AT wangkun tetraaquadiazidocobaltii44dicarboxylato11ethylenedipyridiniumdihydrate
AT wangyanqin tetraaquadiazidocobaltii44dicarboxylato11ethylenedipyridiniumdihydrate
AT zhangjianyong tetraaquadiazidocobaltii44dicarboxylato11ethylenedipyridiniumdihydrate
AT gaoenqing tetraaquadiazidocobaltii44dicarboxylato11ethylenedipyridiniumdihydrate

Ejemplares similares