catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]

The Pb(II) atom in the polymeric title compound, [Pb(C(8)H(4)O(4))(C(12)H(6)N(2)O(2))](n), is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The Pb(II) atom is stereochemically active in a ψ-square-pyramidal coordination geometry in...

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Detalles Bibliográficos
Autores principales: Cong, Fang-Di, Yu, Feng-Yang, Wei, Zhen, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971762/
https://www.ncbi.nlm.nih.gov/pubmed/21578584
http://dx.doi.org/10.1107/S1600536809046455
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author Cong, Fang-Di
Yu, Feng-Yang
Wei, Zhen
Ng, Seik Weng
author_facet Cong, Fang-Di
Yu, Feng-Yang
Wei, Zhen
Ng, Seik Weng
author_sort Cong, Fang-Di
collection PubMed
description The Pb(II) atom in the polymeric title compound, [Pb(C(8)H(4)O(4))(C(12)H(6)N(2)O(2))](n), is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The Pb(II) atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pb⋯O inter­actions are considered, the geometry is a ψ-dodeca­hedron.
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spelling pubmed-29717622010-12-30 catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)] Cong, Fang-Di Yu, Feng-Yang Wei, Zhen Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(II) atom in the polymeric title compound, [Pb(C(8)H(4)O(4))(C(12)H(6)N(2)O(2))](n), is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The Pb(II) atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pb⋯O inter­actions are considered, the geometry is a ψ-dodeca­hedron. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971762/ /pubmed/21578584 http://dx.doi.org/10.1107/S1600536809046455 Text en © Cong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cong, Fang-Di
Yu, Feng-Yang
Wei, Zhen
Ng, Seik Weng
catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_full catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_fullStr catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_short catena-Poly[[(1,10-phenanthroline-5,6-dione-κ(2) N,N′)lead(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_sort catena-poly[[(1,10-phenanthroline-5,6-dione-κ(2) n,n′)lead(ii)]-μ-terephthalato-κ(2) o (1):o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971762/
https://www.ncbi.nlm.nih.gov/pubmed/21578584
http://dx.doi.org/10.1107/S1600536809046455
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