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Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
The asymmetric unit of the title compound, [Mo(2)(η(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units w...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971763/ https://www.ncbi.nlm.nih.gov/pubmed/21578585 http://dx.doi.org/10.1107/S1600536809046327 |
| _version_ | 1782190662409519104 |
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| author | Shultz, Ginger Zakharov, Lev N. Tyler, David R |
| author_facet | Shultz, Ginger Zakharov, Lev N. Tyler, David R |
| author_sort | Shultz, Ginger |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Mo(2)(η(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η(5)-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand. |
| format | Text |
| id | pubmed-2971763 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29717632010-12-30 Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate Shultz, Ginger Zakharov, Lev N. Tyler, David R Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mo(2)(η(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η(5)-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2971763/ /pubmed/21578585 http://dx.doi.org/10.1107/S1600536809046327 Text en © Shultz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shultz, Ginger Zakharov, Lev N. Tyler, David R Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title | Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title_full | Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title_fullStr | Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title_full_unstemmed | Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title_short | Tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate |
| title_sort | tetracarbonylbis(η(5)-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(mo—mo) tetrahydrofuran disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971763/ https://www.ncbi.nlm.nih.gov/pubmed/21578585 http://dx.doi.org/10.1107/S1600536809046327 |
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