(3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione

In the title mol­ecule, C(26)H(20)F(3)N(3)O(2), the two central five-membered rings form a dihedral angle of 62.94 (8)°. The absolute configuration was determined by analysis of Bijvoet pairs based on resonant scattering of light atoms, yielding a Hooft parameter y = −0.05 (11). Notable intra- and i...

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Detalles Bibliográficos
Autores principales: Fronczek, Chris F., Dürüst, Yaşar, Yildirim, Muhammet, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971765/
https://www.ncbi.nlm.nih.gov/pubmed/21578907
http://dx.doi.org/10.1107/S1600536809049319
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author Fronczek, Chris F.
Dürüst, Yaşar
Yildirim, Muhammet
Fronczek, Frank R.
author_facet Fronczek, Chris F.
Dürüst, Yaşar
Yildirim, Muhammet
Fronczek, Frank R.
author_sort Fronczek, Chris F.
collection PubMed
description In the title mol­ecule, C(26)H(20)F(3)N(3)O(2), the two central five-membered rings form a dihedral angle of 62.94 (8)°. The absolute configuration was determined by analysis of Bijvoet pairs based on resonant scattering of light atoms, yielding a Hooft parameter y = −0.05 (11). Notable intra- and inter­molecular contacts include C—H⋯O and C—H⋯π(arene) hydrogen bonds.
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spelling pubmed-29717652010-12-30 (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione Fronczek, Chris F. Dürüst, Yaşar Yildirim, Muhammet Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(26)H(20)F(3)N(3)O(2), the two central five-membered rings form a dihedral angle of 62.94 (8)°. The absolute configuration was determined by analysis of Bijvoet pairs based on resonant scattering of light atoms, yielding a Hooft parameter y = −0.05 (11). Notable intra- and inter­molecular contacts include C—H⋯O and C—H⋯π(arene) hydrogen bonds. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971765/ /pubmed/21578907 http://dx.doi.org/10.1107/S1600536809049319 Text en © Fronczek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fronczek, Chris F.
Dürüst, Yaşar
Yildirim, Muhammet
Fronczek, Frank R.
(3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title_full (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title_fullStr (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title_full_unstemmed (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title_short (3aR,6aR)-1-Phenyl-5-[(R)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3aH,5H)-dione
title_sort (3ar,6ar)-1-phenyl-5-[(r)-1-phenyl­ethyl]-3-[4-(trifluoro­meth­yl)phen­yl]-1,6a-dihydro­pyrrolo[3,4-c]pyrazole-4,6(3ah,5h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971765/
https://www.ncbi.nlm.nih.gov/pubmed/21578907
http://dx.doi.org/10.1107/S1600536809049319
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