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(2,2′-Bipyridine-κ(2) N,N′)diiodidopalladium(II)
The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two iodi...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971767/ https://www.ncbi.nlm.nih.gov/pubmed/21578618 http://dx.doi.org/10.1107/S1600536809047771 |
| Sumario: | The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two iodide ions. The compound displays intermolecular π–π interactions between the pyridine rings of the ligand, the shortest centroid–centroid distance being 4.220 (4) Å. |
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