(2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)

The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two iodi...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971767/
https://www.ncbi.nlm.nih.gov/pubmed/21578618
http://dx.doi.org/10.1107/S1600536809047771
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two iodide ions. The compound displays inter­molecular π–π inter­actions between the pyridine rings of the ligand, the shortest centroid–centroid distance being 4.220 (4) Å.
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spelling pubmed-29717672010-12-30 (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two iodide ions. The compound displays inter­molecular π–π inter­actions between the pyridine rings of the ligand, the shortest centroid–centroid distance being 4.220 (4) Å. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971767/ /pubmed/21578618 http://dx.doi.org/10.1107/S1600536809047771 Text en © Kwang Ha 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title_full (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title_short (2,2′-Bipyridine-κ(2) N,N′)diiodido­palladium(II)
title_sort (2,2′-bipyridine-κ(2) n,n′)diiodido­palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971767/
https://www.ncbi.nlm.nih.gov/pubmed/21578618
http://dx.doi.org/10.1107/S1600536809047771
work_keys_str_mv AT hakwang 22bipyridinek2nndiiodidopalladiumii

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