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trans-Diacetonitriletetrakis(1H-pyrazole-κN (2))nickel(II) dinitrate
In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octahedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex mol...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971772/ https://www.ncbi.nlm.nih.gov/pubmed/21578686 http://dx.doi.org/10.1107/S1600536809049472 |
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author | Chen, Chien-Hong Hsieh, Chang-Chih Lee, Hon Man Horng, Yih-Chern |
author_facet | Chen, Chien-Hong Hsieh, Chang-Chih Lee, Hon Man Horng, Yih-Chern |
author_sort | Chen, Chien-Hong |
collection | PubMed |
description | In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octahedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex molecules into one-dimensional chains running parallel to [100]. |
format | Text |
id | pubmed-2971772 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29717722010-12-30 trans-Diacetonitriletetrakis(1H-pyrazole-κN (2))nickel(II) dinitrate Chen, Chien-Hong Hsieh, Chang-Chih Lee, Hon Man Horng, Yih-Chern Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octahedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex molecules into one-dimensional chains running parallel to [100]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971772/ /pubmed/21578686 http://dx.doi.org/10.1107/S1600536809049472 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Chien-Hong Hsieh, Chang-Chih Lee, Hon Man Horng, Yih-Chern trans-Diacetonitriletetrakis(1H-pyrazole-κN (2))nickel(II) dinitrate |
title |
trans-Diacetonitriletetrakis(1H-pyrazole-κN
(2))nickel(II) dinitrate |
title_full |
trans-Diacetonitriletetrakis(1H-pyrazole-κN
(2))nickel(II) dinitrate |
title_fullStr |
trans-Diacetonitriletetrakis(1H-pyrazole-κN
(2))nickel(II) dinitrate |
title_full_unstemmed |
trans-Diacetonitriletetrakis(1H-pyrazole-κN
(2))nickel(II) dinitrate |
title_short |
trans-Diacetonitriletetrakis(1H-pyrazole-κN
(2))nickel(II) dinitrate |
title_sort | trans-diacetonitriletetrakis(1h-pyrazole-κn
(2))nickel(ii) dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971772/ https://www.ncbi.nlm.nih.gov/pubmed/21578686 http://dx.doi.org/10.1107/S1600536809049472 |
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