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trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate

In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octa­hedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex mol­...

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Detalles Bibliográficos
Autores principales: Chen, Chien-Hong, Hsieh, Chang-Chih, Lee, Hon Man, Horng, Yih-Chern
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971772/
https://www.ncbi.nlm.nih.gov/pubmed/21578686
http://dx.doi.org/10.1107/S1600536809049472
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author Chen, Chien-Hong
Hsieh, Chang-Chih
Lee, Hon Man
Horng, Yih-Chern
author_facet Chen, Chien-Hong
Hsieh, Chang-Chih
Lee, Hon Man
Horng, Yih-Chern
author_sort Chen, Chien-Hong
collection PubMed
description In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octa­hedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex mol­ecules into one-dimensional chains running parallel to [100].
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spelling pubmed-29717722010-12-30 trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate Chen, Chien-Hong Hsieh, Chang-Chih Lee, Hon Man Horng, Yih-Chern Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(CH(3)CN)(2)(C(3)H(4)N(2))(4)](NO(3))(2), the cation lies on an inversion center and adopts an octa­hedral coordination geometry about the Ni atom. The two acetonitrile ligands are in a trans conformation. N—H⋯O hydrogen bonds between cations and anions link the complex mol­ecules into one-dimensional chains running parallel to [100]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971772/ /pubmed/21578686 http://dx.doi.org/10.1107/S1600536809049472 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Chien-Hong
Hsieh, Chang-Chih
Lee, Hon Man
Horng, Yih-Chern
trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title_full trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title_fullStr trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title_full_unstemmed trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title_short trans-Diacetonitrile­tetra­kis(1H-pyrazole-κN (2))nickel(II) dinitrate
title_sort trans-diacetonitrile­tetra­kis(1h-pyrazole-κn (2))nickel(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971772/
https://www.ncbi.nlm.nih.gov/pubmed/21578686
http://dx.doi.org/10.1107/S1600536809049472
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