(Dimethyl sulfoxide-κO)di­phenyl­(3-thioxo-3H-1,2-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))tin(IV)

The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiol­ate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide mol­ecule...

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Detalles Bibliográficos
Autores principales: Comerlato, Nadia M., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971776/
https://www.ncbi.nlm.nih.gov/pubmed/21578622
http://dx.doi.org/10.1107/S1600536809047904
Descripción
Sumario:The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiol­ate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide mol­ecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related mol­ecules associate via pairs of C—H⋯S contacts, forming dimeric aggregates.

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