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(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV)
The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971776/ https://www.ncbi.nlm.nih.gov/pubmed/21578622 http://dx.doi.org/10.1107/S1600536809047904 |
| _version_ | 1782190666429759488 |
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| author | Comerlato, Nadia M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
| author_facet | Comerlato, Nadia M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
| author_sort | Comerlato, Nadia M. |
| collection | PubMed |
| description | The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related molecules associate via pairs of C—H⋯S contacts, forming dimeric aggregates. |
| format | Text |
| id | pubmed-2971776 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29717762010-12-30 (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV) Comerlato, Nadia M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related molecules associate via pairs of C—H⋯S contacts, forming dimeric aggregates. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2971776/ /pubmed/21578622 http://dx.doi.org/10.1107/S1600536809047904 Text en © Comerlato et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Comerlato, Nadia M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2) S (4),S (5))tin(IV) |
| title | (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_full | (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_fullStr | (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_full_unstemmed | (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_short | (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ(2)
S
(4),S
(5))tin(IV) |
| title_sort | (dimethyl sulfoxide-κo)diphenyl(3-thioxo-3h-1,2-dithiole-4,5-dithiolato-κ(2)
s
(4),s
(5))tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971776/ https://www.ncbi.nlm.nih.gov/pubmed/21578622 http://dx.doi.org/10.1107/S1600536809047904 |
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